Bio-inspired Catalysis and Materials Lab
Indian Institute of Science Education and Research, Kolkata, Nadia, Mohanpur-741246, India
Bio-Inspired Catalysis
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The Equatorial Ligand Effect on the Properties and Reactivity of Iron(V) Oxo Intermediates Santanu Pattanayak, Fabián G. Cantú Reinhard, Atanu Rana, Sayam Sen Gupta* and Sam P. de Visser*, Chem. Eur. J., 2019, 25, 8092–8104. https://doi.org/10.1002/chem.201900708
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Catalytic oxidation of alcohols using Fe-bTAML and NaClO: Comparing the reactivity of Fe(V)O and Fe(IV)O intermediates Sandipan Jana, Jithin Thomas and Sayam Sen Gupta*, Inorg. Chim. Acta, 2019, 486, 476-482, https://doi.org/10.1016/j.ica.2018.10.067
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Poulami Majumder, Ananda Basak, Himangshu Kuiry, Himadri Sekhar Sasmal, Suvendu Karak, Paramita Saha, Bittu Chandra, Sayam Sen Gupta* and Rahul Banerjee*
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J. Am. Chem. Soc. 2023
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Sandipan Jana,Santanu Pattanayak,Soumadip Das, Munmun Ghosh,Lucia Velasco, Dooshaye Moonshiram and Sayam Sen Gupta* Chem. Commun., 2023, 59, 2755
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Heterogeneous C–H Functionalization in Water via Porous Covalent Organic Framework Nanofilms: A Case of Catalytic Sphere Transmutation
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Himadri Sekhar Sasmal, Saikat Bag, Bittu Chandra, Poulami Majumder, Himangshu Kuiry, Suvendu Karak, Sayam Sen Gupta*, and Rahul Banerjee* J. Am. Chem. Soc. 2021, 143, 22, 8426–8436, https://doi.org/10.1021/jacs.1c02425
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Oxoiron(V) mediated selective electrochemical oxygenation of unactivated C-H and C=C bonds using water as oxygen source
Bittu Chandra, K. M. Hellan, Santanu Pattanayak and Sayam Sen Gupta*, Chem. Sci. Sci., 2020, 56, 8484-8487, https://doi.org/10.1039/D0SC03616A
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Selective oxygenation of unactivated C-H bonds by dioxygen via an autocatalytic formation of oxoiron(V) species
Bittu Chandra, Puja De and Sayam Sen Gupta*, Chem. Commun., 2020, 56, 8484-8487 https://doi.org/10.1039/D0CC03071F
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Coordination chemistry of carboxamide ‘Nx’ ligands to metal ions for bio-inspired catalysis (Dedicated to Prof. Goutam Kumar Lahiri on his 65th birthday)
Chakadola Panda, Aniruddha Sarkar and Sayam Sen Gupta*, Coord. Chem. Rev., 2020, 417, 213314, https://doi.org/10.1016/j.ccr.2020.213314
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Selective photocatalytic hydroxylation and epoxidation reactions by an iron complex using water as the oxygen source Bittu Chandra, Kundan K. Singh, Sayam Sen Gupta* Chem. Sci., 2017,8, 7545-7551
https://doi.org/10.1039/C7SC02780J
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Selective C-H Bond Oxidation Catalyzed by Fe-bTAML complex: Mechanistic Implications Munmun Ghosh, Santanu Pattanayak, Basab Dhar, Kundan Singh, Chakadola Panda and Sayam Sen Gupta* Inorg. Chem. 2017, 56, 10852-10860 https://doi.org/10.1021/acs.inorgchem.7b00453
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Reductive Activation of O2 by Bioinspired Fe-Complex for Catalytic Epoxidation Reactions Kundan K. Singh and Sayam Sen Gupta* Chem. Commun. 2017, 53, 5914-5917 https://doi.org/10.1039/C7CC00933J
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Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units Santanu Pattanayak, Andrew J. Jasniewski, Atanu Rana, Apparao Draksharapu, Kundan K. Singh, Andrew Weitz, Michael Hendrich, Lawrence Que Jr.,* Abhishek Dey* and Sayam Sen Gupta* Inorg. Chem. 2017, 56 (11), 6352-6361 https://doi.org/10.1021/acs.inorgchem.7b00448
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Electrochemical formation of FeV(O) and mechanism of its reaction with water during O-O bond formation Santanu Pattanayak, Debarati Roy Chowdhury, Bikash Garai, Kundan K. Singh, Amit Paul,* Basab B Dhar,* Sayam Sen Gupta* Chem. Eur. J. 2017 23(14), 3414
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Iron Complex Catalyzed Selective C-H Bond Oxidation with Broad Substrate Scop Sandipan Jana, Munmun Ghosh, Mayur Ambule, and Sayam Sen Gupta* Org. Lett., 2017, 19, 746
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Electrocatalytic water oxidation by a molecular cobalt complex through a high valent cobalt oxo intermediate Debasree Das, Santanu Pattanayak, Kundan K. Singh, Bikash Garai and Sayam Sen Gupta Chem Commun 2016, 52, 11787
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Catalytic Macroporous Biohydrogels Made of Ferritin-Encapsulated Gold Nanoparticles Sushma Kumari, Marleen Haring, Sayam Sen Gupta,* and David Diaz Diaz* ChemPlusChem, DOI: 10.1002/cplu.201600454
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Mechanism of Alcohol Oxidation by FeV(O) at Room Temperature Munmun Ghosh, Y. L. K. Nikhil, Basab B. Dhar, and Sayam Sen Gupta* Inorg Chem, 2015, 54, 11792
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Molecular Fe-complex as a catalyst probe for in-gel visual detection of proteins via signal amplification Sushma Kumari, Chakadola Panda, S. Mazumdar and Sayam Sen Gupta* Chem. Commun., 2015, 51, 15257
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Mechanism of Oxygen Atom Transfer from FeV(O) to Olefins at Room Temperature Kundan Singh, Mrityunjay Tiwari, Basab B Dhar, Kumar Vanka* and Sayam Sen Gupta* Inorg. Chem. 2015, 54, 6112
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Tuning the Reactivity of FeV(O) toward C–H Bonds at Room Temperature: Effect of Water Kundan Singh, Mrityunjay Tiwari, Munmun Ghosh, Chakadola Panda, Andrew Weitz, Michael P. Hendrich, Basab B Dhar, Kumar Vanka and Sayam Sen Gupta* Inorg. Chem., 2015, 54 (4), 1535
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Fe-TAML Encapsulated inside Mesoporous Silica Nanoparticles as Peroxidase Mimic: Femtomolar Protein Detection Sushma Kumari, Basab B. Dhar, Chakadola Panda, Abhishek Meena, and Sayam Sen Gupta* ACS Applied Materials and Interfaces, 2014, 6(16), 13866
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Investigation of C–C Bond Formation Mediated by Bombyx mori Silk Fibroin Materials Dennis Kühbeck, Munmun Ghosh, Sayam Sen Gupta, and David Díaz Díaz * ACS Sustainable Chem. Eng., 2014, 2 (6), 1510
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Homogeneous Photochemical Water Oxidation by Biuret Modified Fe-TAML: Evidence of FeV(O) Intermediate Chakadola Panda, Joyashish Debgupta, David Díaz Díaz, Kundan K. Singh, Sayam Sen Gupta* and Basab B. Dhar* J. Am. Chem. Soc. 2014, 136, pp 12273
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Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C–H Bonds Munmun Ghosh, Kundan K. Singh, Chakadola Panda, Andrew Weitz, Michael P. Hendrich , Terrence J. Collins, Basab B. Dhar *, and Sayam Sen Gupta * J. Am. Chem. Soc., 2014, 136 (27), 9524 Appeared as a Cover Page in July 9th Issue
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Catalytic signal amplification using [FeIII(biuret-amide)]-mesoporous silica nanoparticles: visual cyanide detection Chakadola Panda, Basab B. Dhar, Bharmana Malvi, Yudhajit Bhattacharjee and Sayam Sen Gupta* Chem. Commun., 2013, 49, 2216
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Development of a multifunctional catalyst for a “relay” reaction Anal Kr. Ganai, Pravin Shinde, Basab B. Dhar, Sayam Sen Gupta* and B. L. V. Prasad RSC Adv., 2013,3, 2186
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One pot glucose detection by [FeIII(biuret-amide)] immobilized on mesoporous silica nanoparticles: an efficient HRP mimic Bharmana Malvi , Chakadola Panda , Basab B. Dhar and Sayam Sen Gupta* Chemical Communications, 2012, 48 (43), 5289
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Fe(III) complex of biuret-amide based macrocyclic ligand as peroxidase enzyme mimic Chakadola Panda, Munmun Ghosh, Tamas Panda, Rahul Banerjee, Sayam Sen Gupta*, Chemical Communications, 2011, 47, 8016
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‘Clicking’ molecular hooks on silica nanoparticles to immobilize catalytically important metal complexes: the case of gold catalyst immobilization Anal Kr. Ganai, Rima Bhardwaj, Srinivas Hotha,* Sayam Sen Gupta* and B. L. V. Prasad*, New J. Chem, 2010, 34, 2662
Publications: PhD and Post-doc
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“CPMV as a scaffold for generation of specific antibodies against complex carbohydrates” Eiton Kaltgrad, Sayam Sen Gupta, Sreenivas Punna, Ola Blixt*, and M. G. Finn*, ChemBioChem, 2007, 8, 1455
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“Nickel(II) and Copper(II) Bis(Formamidine Urea) Complexes: Synthesis, Characterization, and Reactivity Studies” David D. Diaz, Sayam Sen Gupta, Jane Kuzelka, and M. G. Finn*, European Journal of Inorganic Chemistry, 2006, 22, 4489
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“Accelerated Bioorthogonal Conjugation: A Practical Method for the Ligation of Diverse Functional Molecules to a Polyvalent Virus Scaffold” Sayam Sen Gupta, Jane Kuzelka, Pratik Singh, Warren G. Lewis, Marianne Manchester and M. G. Finn* Bioconjugate Chemistry, 2005, 16(6),1572
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“Virus-Glycopolymer Conjugates by Copper(I) Catalysis of Atom Transfer Radical Polymerization and Azide-Alkyne Cycloaddition” Sayam Sen Gupta, Krishnaswami S. Raja, Eiton Kaltgrad, Erica Strable, and M.G. Finn* Chemical Communications, 2005, 4315.
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“Understanding the Mechanism of H+-Induced Demetalation as a Design Strategy for Robust Iron(III) Peroxide-Activating Catalysts” Anindya Ghosh, Alexander D. Ryabov, Sherry M. Mayer, David C. Horner, Duane E. Prasuhn, Jr., Sayam Sen Gupta, Leonard Vuocolo, Caleb Culver, Michael P. Hendrich,* Cliffton E. F. Rickard, Richard E. Norman, Colin P. Horwitz, and Terrence J. Collins* J. Am. Chem. Soc. 2003, 125 (41), 12378. This work was featured as “Editors Choice” in Science entitled “The Iron Grip” (Vol 302, Oct 17, 2003, page 359
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“Rapid total destruction of chlorophenols by activated hydrogen peroxide” Sayam Sen Gupta; Matthew Stadler; Christopher A Noser; Anindya Ghosh; Bradley Steinhoff; Dieter Lenoir; Colin P Horwitz; Karl-Werner Schramm; Terrence J Collins* Science 2002, 296, 326 This work was featured as “News and Views” in Science as “Degradation of Chlorinated Phenols” (Vol 296, April 12, 2002, page 270); in Chem. & Eng. News in the article “Green Chemistry Gets Greener” (May 20, 2002) and in the newspaper VDI Nachrichten, Duesseldorf, Germany as “Mit Kat gegen Chlorphenol” (April 10, 2002)
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“Green chemistry: sustaining a high-technology civilization” Anindya Ghosh; Sayam Sen Gupta; Michael J. Bartos; Yelda Hangun; Leonard D. Vuocolo; Bradley A. Steinhoff; Christopher A. Noser; David Horner; Sherry Mayer; Kevin Inderhees; Colin P. Horwitz; Jonathan Spatz; Alexander D. Ryabov; Sujit Mondal; Terrence J. Collins Pure Appl. Chem. 2001, 73(1), 113
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“Synthesis and Characterization of a New Generation of Cryptand-Based Triple-Tailed Amphiphiles: Spontaneous Formation of Vesicles and X-ray Crystallographic Studies” Pradyut Ghosh; Sayam Sen Gupta; Parimal K Bharadwaj. Langmuir 1998, 14(20), 5712
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“Complexation properties of a heteroditopic cryptand towards Cu(II) and Ni(II), crystal structures of the cryptand and its nickel(II) cascade complex” Pradyut Ghosh; Sayam Sen Gupta; Parimal K Bharadwaj J. Chem. Soc., Dalton Trans. 1997, 6, 935.